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Tech brief: Hydrogen classification systems

Hydrogen can be produced in many different ways and from different feedstocks. The choice of method and feedstock gives rise to more or less greenhouse gas emissions. In the general discourse on hydrogen and climate change, it is essential to distinguish between different types of hydrogen. As a result, systems have emerged to classify hydrogen, the most commonly known and used being colors. However, the European Commission has introduced one that focuses more on emissions. This tech brief explains the two systems.

What col­or does hydro­gen have? None at all. It is trans­par­ent and can­not be seen with the naked eye. How­ever, hydro­gen is called black, brown, gray, blue, green, and so forth. The col­ors denote the feed­stocks and pro­duc­tion meth­ods used to pro­duce hydro­gen. In this brief, we explain the mean­ing of the dif­fer­ent col­ors and look at an altern­at­ive clas­si­fic­a­tion of hydro­gen used by the EU.

Colors of hydrogen

Let’s start by review­ing the col­or spec­trum used to clas­si­fy hydro­gen based on how it is pro­duced and with which feedstock.

  • Black hydro­gen is pro­duced by coal gas­i­fic­a­tion of black coal (bitu­min­ous).
  • Brown hydro­gen is pro­duced by coal gas­i­fic­a­tion of brown coal (lig­nite) or bio­mass gasification.
  • Grey hydro­gen is pro­duced by steam meth­ane reform­ing, par­tial oxid­a­tion, or auto­therm­al reform­ing of nat­ur­al gas and oil.
  • Blue hydro­gen is pro­duced as black, brown, or grey hydro­gen with the added applic­a­tion of car­bon cap­ture, util­iz­a­tion, and stor­age (CCUS) meth­ods or technologies.
  • Tur­quoise hydro­gen is pro­duced by meth­ane pyrolysis.
  • Yel­low hydro­gen is pro­duced by water elec­tro­lys­is using elec­tri­city from the grid regard­less of how this elec­tri­city has been produced.
  • Pink hydro­gen is pro­duced by water elec­tro­lys­is using elec­tri­city from nuc­le­ar power.
  • Purple hydro­gen is pro­duced by ther­mo­chem­ic­al water split­ting using energy from nuc­le­ar power.
  • Red hydro­gen is pro­duced by high-tem­per­at­ure cata­lyt­ic split­ting of water using energy from nuc­le­ar power.
  • Green hydro­gen is pro­duced by water elec­tro­lys­is using renew­able energy sources.
  • White hydro­gen is nat­ur­ally occur­ring hydro­gen found as a free gas in lay­ers of con­tin­ent­al crust, deep in the ocean­ic crust, or in vol­can­ic gases, gey­sers, and hydro­therm­al systems.

The list above can be sum­mar­ized in this schem­at­ic table illus­trat­ing the rela­tion­ships between the dif­fer­ent col­or classes used for hydro­gen and the feed­stock and pro­cess used to pro­duce it.

Feed­stock Pro­duc­tion method Hydro­gen color
Nat­ur­al gas Meth­ane pyrolysis Tur­quoise
Steam reform­ing Gray Blue (if car­bon is captured) Yel­low (if used to pro­duce elec­tri­city for water electrolysis)
Black coal Gas­si­fic­a­tion Black
Brown coal Gas­si­fic­a­tion Brown
Bio­mass
Renew­able electricity Water elec­tro­lys­is Green
Nuc­le­ar electricity Water elec­tro­lys­is Pink
Water split­ting Purple
Cata­lyt­ic splitting Red

Caveat

The hydro­gen industry’s col­or clas­si­fic­a­tion is evolving, and not all terms have uni­ver­sally agreed-upon defin­i­tions. This can lead to vari­ations in how terms are used and understood.

Yel­low hydro­gen is an example that shows vari­ation in how terms are used. Above, it’s described as hydro­gen pro­duced by water elec­tro­lys­is, where the elec­tri­city comes from the grid and, there­fore, can be pro­duced by any­thing from coal-fired power sta­tions to wind tur­bines. But quite a few people have a com­pletely dif­fer­ent defin­i­tion: Yel­low hydro­gen is pro­duced by water elec­tro­lys­is using elec­tri­city from sol­ar power plants. This is an entirely dif­fer­ent defin­i­tion far from the one used by most inter­na­tion­al organ­iz­a­tions, gov­ern­ments, author­it­ies, and researchers.

Green hydro­gen is an example that shows vari­ation in how terms are under­stood. Above, it’s described as hydro­gen pro­duced by water elec­tro­lys­is, where the elec­tri­city comes from any renew­able source. Bio­mass is an example of a renew­able source, but it’s not very” green” when used as fuel in power plants. There­fore, the EU Com­mis­sion and Par­lia­ment use a defin­i­tion of green hydro­gen that excludes bio­mass and also requires at least a 70 per­cent reduc­tion in green­house gas emis­sions com­pared to fossil fuels.

In addi­tion, some use viol­et instead of pink, and oth­ers con­flate pink, purple, and red hydro­gen and use one of these col­ors to mean all of them.

On top of that, research­ers and developers slap new col­ors on each nov­el meth­od of cre­at­ing hydro­gen. For example, aqua is used for hydro­gen extrac­ted from oil sands and oil fields, and orange is used for hydro­gen pro­duced by chem­ic­al reac­tions in iron-rich under­ground formations.

EU classification

How­ever, as we have seen, there is no con­sensus on which col­ors to use and what they stand for. This has promp­ted the European Com­mis­sion to intro­duce its own clas­si­fic­a­tion in the commission’s hydro­gen strategy for a cli­mate-neut­ral Europe:

  • Elec­tri­city-based hydro­gen is hydro­gen pro­duced through water elec­tro­lys­is regard­less of the elec­tri­city source. (Thus, includes both yel­low and green hydrogen).
  • Renew­able hydro­gen is hydro­gen pro­duced through water elec­tro­lys­is with elec­tri­city from renew­able sources. (Thus, it’s a large sub­set of green hydrogen).
  • Clean hydro­gen is anoth­er name for renew­able hydrogen.
  • Fossil-based hydro­gen is hydro­gen pro­duced through vari­ous pro­cesses using fossil fuels as feed­stock. (Thus, this includes black, brown, gray, and blue hydrogen.)
  • Fossil-based hydro­gen with car­bon cap­ture is a sub­part of fossil-based hydro­gen, but where green­house gases emit­ted as part of the hydro­gen pro­duc­tion pro­cess are cap­tured. (Thus, this is equi­val­ent to blue hydrogen.)
  • Low-car­bon hydro­gen encom­passes fossil-based hydro­gen with car­bon cap­ture and elec­tri­city-based hydro­gen, with sig­ni­fic­antly reduced full life-cycle green­house gas emis­sions com­pared to exist­ing hydro­gen pro­duc­tion. As of Feb­ru­ary 7, 2023, this means at least a 70% reduc­tion in green­house gas emis­sions com­pared to fossil fuels. (Thus, this con­tains a sub­set of blue hydro­gen and a sub­set of yel­low hydrogen.)
  • Hydro­gen-derived syn­thet­ic fuels refer to vari­ous gaseous and liquid fuels based on hydro­gen and car­bon. (Thus, this has no equi­val­ent color.)

The table below illus­trates the rela­tion­ships between the European Com­mis­sion clas­si­fic­a­tion and the col­or classification.

Hydro­gen col­or classification EU hydro­gen classification
Black Fossil-based hydro­gen
Brown
Gray
Blue Fossil-based hydro­gen with car­bon capture
Low-car­bon hydrogen
Tur­quoise Low-car­bon hydrogen
Red
Purple
Pink Elec­tri­city-based hydrogen
Yel­low
Green Renew­able hydrogen

Purpose of classification

The clas­si­fic­a­tion of hydro­gen helps vari­ous groups like politi­cians, busi­ness lead­ers, and envir­on­ment­al­ists to quickly identi­fy its pro­duc­tion impact on the envir­on­ment. This clas­si­fic­a­tion sep­ar­ates hydro­gen with high green­house gas emis­sions (black, brown, and gray) from low-emis­sion (blue) and com­pletely fossil-free types (pink and green).

Present and future

In 2022, almost 95 mil­lion tonnes (Mt) of hydro­gen were pro­duced glob­ally, accord­ing to Glob­al Hydro­gen Review 2023. 99.3% was fossil-based hydro­gen (black, brown, or gray). Only 0.6% was fossil-based hydro­gen with car­bon cap­ture (blue). And pity 0.1% was elec­tri­city-based or renew­able hydro­gen (pink, yel­low, or green).

Over the next six years, the Glob­al Hydro­gen Review 2023 pre­dicts a sharp increase in demand. The demand is expec­ted to increase by more than 50%, reach­ing 150 tons of hydro­gen by 2030.

Ana­lysts and experts gen­er­ally believe that vir­tu­ally all of this increase will con­sist of hydro­gen pro­duced by water elec­tro­lys­is. Data from the Hydro­gen Pro­duc­tion and Infra­struc­ture Pro­jects Data­base shows that in Octo­ber 2023, there were over 1,500 planned or ongo­ing con­struc­tions of elec­tro­lyz­er plants to be com­pleted by 2030. Togeth­er, they will gen­er­ate 92 Mt of hydro­gen, of which 66 Mt are green, 4 Mt are yel­low, and the rest are unspecified.

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